Crystal Structure of [μ-13,27-di-<i>tert</i>-butyl-3,6,9,17,20,23-hexaazatri- cyclo [23,3,1,1^11,15^]triaconta-1(28),11,13,15 (30),25,26-hexaene-29,30-diolato[κ^5^<i>N^3^</i>,<i>N^6^</i>,<i>N^9^</i>,\ <i>O^29^</i>,<i>O^30^</i>:κ^5^<i>N^17^</i>,<i>N^20^</i>,<i>N^23^</i>,\ <i>O^29^</i>,<i>O^30^</i>]bis(thiocyanato-κN)cobalt(II)—–methanol (1:2)
Id | 8102583 |
Common name | [μ-13,27-di-<i>tert</i>-butyl-3,6,9,17,20,23-hexaazatri- cyclo [23,3,1,1^11,15^]triaconta-1(28),11,13,15 (30),25,26-hexaene-29,30-diolato[κ^5^<i>N^3^</i>,<i>N^6^</i>,<i>N^9^</i>,\ <i>O^29^</i>,<i>O^30^</i>:κ^5^<i>N^17^</i>,<i>N^20^</i>,<i>N^23^</i>,\ <i>O^29^</i>,<i>O^30^</i>]bis(thiocyanato-κN)cobalt(II)—–methanol (1:2) |
Chemical name | [μ-13,27-di-<i>tert</i>-butyl-3,6,9,17,20,23-hexaazatri- cyclo [23,3,1,1^11,15^]triaconta-1(28),11,13,15 (30),25,26-hexaene-29,30-diolato[κ^5^<i>N^3^</i>,<i>N^6^</i>,<i>N^9^</i>,\ <i>O^29^</i>,<i>O^30^</i>:κ^5^<i>N^17^</i>,<i>N^20^</i>,<i>N^23^</i>,\ <i>O^29^</i>,<i>O^30^</i>]bis(thiocyanato-κN)cobalt(II)—–-methanol (1:2) |
a (Å) | 8.4580(17) |
b (Å) | 10.448(2) |
c (Å) | 12.553(3) |
α (°) | 77.44(3) |
β (°) | 79.73(3) |
γ (°) | 82.19(3) |
V (Å3) | 1059.9(4) |
Space group | P -1 |
Temperature (K) | 293(2) |
Rint | 0.0528 |
Publication: Zeitschrift für Kristallographie - New Crystal Structures (2010) 225, 1 49