Crystal Structure of [(η^5^-C~5~Me~5~)Ru{κ^2^-C,N-(=C-CH(SC~5~H~4~N)=CPh~2~} {κ^1^ P-^i^Pr~2~PNH(C~5~H~4~N)}][PF~6~].0.49 (CH~2~Cl~2~)
Id | 4063892 |
Common name | [(η^5^-C~5~Me~5~)Ru{κ^2^-C,N-(=C-CH(SC~5~H~4~N)=CPh~2~} {κ^1^ P-^i^Pr~2~PNH(C~5~H~4~N)}][PF~6~].0.49 (CH~2~Cl~2~) |
Chemical name | {(diisopropyl-phosphanyl)-(pyridin-2-yl)-amine-κ^1^-P}- {1-(2-mercapto-pyridine)-3,3-diphenyl-prop-2-en-1-ylidene—–κ^2^-C,N}- (pentahapto-pentamethyl-cyclopentadienyl)-ruthenium(II) hexafluorophosphate dichloromethane solvate |
a (Å) | 14.700(3) |
b (Å) | 15.636(3) |
c (Å) | 20.907(4) |
α (°) | 90.00 |
β (°) | 109.74(3) |
γ (°) | 90.00 |
V (Å3) | 4523.1(18) |
Space group | P 1 21/c 1 |
Temperature (K) | 100(2) |
Rint | 0.0792 |
Publication: Organometallics (2011) 30, 4 726