Crystal Structure of [(L){Rh(COD)}~2~][PF~6~]~2~ (L = bis{4,5-bis(1-methylene-3- methylimidazolidene)}benzo-18-crown-6; COD = 1,5-cyclooctadiene)

Id2237234
Common name[(L){Rh(COD)}~2~][PF~6~]~2~ (L = bis{4,5-bis(1-methylene-3- methylimidazolidene)}benzo-18-crown-6; COD = 1,5-cyclooctadiene)
Chemical name(μ-3,3,3'',3'''-{[2,5,8,15,18,21- Hexaoxatricyclo[20.4.0.0^9,14^]hexacosa-1(22),9,11,13,23,25-hexaene- 11,12,24,25-tetrayl]tetrakis(methylene)}tetrakis(1-methyl-1<i>H</i>-imidazol- 2-yl))bis[(η^4^-cycloocta-1,4-diene)rhodium(I)] bis(hexafluoridophosphate) acetonitrile sesquisolvate dihydrate
a (Å)10.510(2)
b (Å)15.630(3)
c (Å)23.280(5)
α (°)104.69(3)
β (°)90.20(3)
γ (°)109.58(3)
V (Å3)3468.9(15)
Space groupP -1
Temperature (K)100(2)
Rint0.0509
Publication: Acta Crystallographica Section E (2013) 69, 1 m47-m48