Crystal Structure of [(L){Rh(COD)}~2~][PF~6~]~2~ (L = bis{4,5-bis(1-methylene-3- methylimidazolidene)}benzo-18-crown-6; COD = 1,5-cyclooctadiene)
Id | 2237234 |
Common name | [(L){Rh(COD)}~2~][PF~6~]~2~ (L = bis{4,5-bis(1-methylene-3- methylimidazolidene)}benzo-18-crown-6; COD = 1,5-cyclooctadiene) |
Chemical name | (μ-3,3,3'',3'''-{[2,5,8,15,18,21- Hexaoxatricyclo[20.4.0.0^9,14^]hexacosa-1(22),9,11,13,23,25-hexaene- 11,12,24,25-tetrayl]tetrakis(methylene)}tetrakis(1-methyl-1<i>H</i>-imidazol- 2-yl))bis[(η^4^-cycloocta-1,4-diene)rhodium(I)] bis(hexafluoridophosphate) acetonitrile sesquisolvate dihydrate |
a (Å) | 10.510(2) |
b (Å) | 15.630(3) |
c (Å) | 23.280(5) |
α (°) | 104.69(3) |
β (°) | 90.20(3) |
γ (°) | 109.58(3) |
V (Å3) | 3468.9(15) |
Space group | P -1 |
Temperature (K) | 100(2) |
Rint | 0.0509 |
Publication: Acta Crystallographica Section E (2013) 69, 1 m47-m48